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Framework Ti-substituted and Ti-grafted MCM-41 mesoporous material has been prepared by direct hydrothermal synthesis and a post-synthesis grafting method. The materials have been tested as catalysts for cyclohexene oxidation with aqueous H2O2 and tert-butyl hydroperoxide (TBHP). With aqueous H2O2 in methanol, the major products were cyclohexene diol and its methyl ethers. No cyclohexene oxide was...
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