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The low‐cost and earth‐abundant compound Cu2ZnSn(S,Se)4 (CZTSSe) is emerging as a promising absorber layer in thin‐film photovoltaics technology. To improve the power conversion efficiency in CZTSSe‐based solar cells, different sulphurization methods have been investigated. An important issue is the influence of the growth conditions on the electronic structure and charge carriers dynamics. Teixeira...
The structural and optical properties of two solar cells in which the CuZnSnS absorber layer was sulphurized by two different methods (S flux and graphite box), were studied. The grain sizes are dependent on the sulphurization method, the larger ones being obtained for the sulphurization in a S flux. The optical properties were investigated by photoluminescence (PL). A broad and asymmetric band...
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