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Gold(I) catalysis has been recognized as a valuable tool for the unique transformation of multiple carbon‐carbon bonds. Enantioselective π‐catalysis based on gold(I) complexes is, however, still underdeveloped due to lack of privileged ligands. Herein, we present an accessible method to a new family of stable yet catalytically active chiral NHC−Au(I)−Cl complexes. The key to preserving a simultaneous...
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