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Since the relevance of deactivation phenomena in heterogeneous gas–solid photocatalytic processes, a study on the deactivation of MoO x /TiO 2 catalysts in the oxidative photodehydrogenation of cyclohexane has been carried out in a fixed bed reactor and compared to the behaviour of catalysts used in a two-dimensional fluidized bed photoreactor.Superior photocatalytic performances were...
Heterogeneous oxidative dehydrogenation of cyclohexane to benzene was found to occur under photocatalytic conditions on MoO x /TiO 2 . Initial cyclohexane conversion of 15% and maximum selectivity to benzene of 65% were achieved at 308K on 8wt.% MoO x /TiO 2 under irradiation with a continuous flow reactor. The main by-product was carbon dioxide. Catalyst deactivation...
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