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An amphiphilic lanthanide complex, (E) -1-methyl-4-(2-(4-(dihexadecylamino)phenyl)azo)pyridinium tetrakis( 1-phenyl-3-methyl-4-benzoyl-5-pyrazolonato)lanthanum(III), has been synthesized. It forms a stable Langmuir monolayer film on a pure water subphase (pH 5.6, 18°C) when spread from a chloroform solution. Langmuir-Blodgett (LB) films were prepared by transferring the monolayers onto hydrophilic...
In this paper we report on electroluminescence from Langmuir-Blodgett (LB) films of two novel molecular complexes originally developed for non-linear optics applications containing neodymium and dysprosium trivalent rare earth ions. The two molecular complexes have a structure which consists of a donor π-π * conjugated cation ionically coupled to a complex anion consisting of a trivalent rare...
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