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The results of the X-ray (at 295 and 355K), dilatometric, differential scanning calorimetry and dielectric studies on a new piperidinium crystal, (C5H12N)2SbCl5, are presented. The anionic sublattice of the crystal is built up of infinite (SbCl52−)n chains composed of SbCl63− distorted octahedra connected with each other by corners. In voids of anionic sublattice two crystallographically independent...
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