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The actinomycin D (AMD) analogs in which the d-valine residues (the second amino acid residue in the cyclic depsipeptide of AMD) and the N-methyl-l-valine residues (the fifth amino acid residue in the cyclic depsipeptide of AMD) were replaced with d-Phe or l- and d-forms N-methylvalines, N-methylisoleucine, N-methylleucine, N-methylphenylalanine, N-methylalanine, and sarcosine were synthesized. The...
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