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The role of non-covalent interaction between both non-specifically adsorbed hydrated K+, Li+ and Ba2+ cations (M+) and hydroxyl species (M+-OHad) as well as underpotentially deposited Cu adatoms and OHad (Cuupd-OHad) on bulk CO oxidation (COb) is investigated on Pt(111) and Pt(100) in alkaline solutions. The effect of Cuupd-OHad on COb oxidation is observed almost at the reversible potential for CO...
The role of noncovalent interactions in the hydrogen oxidation reaction (HOR), oxygen reduction reaction (ORR), and hydrogen evolution reaction (HER) on Ru, Ir, and Ru0.5Ir0.5 electrodes is studied in alkaline solution containing K+, Li+, and Ba2+ cations. We found that noncovalent interaction between hydrated cations and covalently bonded OHad increases in the same order as specific charge density...
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