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Größer und besser! Der zwitterionische Gold‐Katalysator, der durch die Koordination eines Phosphanliganden mit dem inerten und nichtkoordinierenden Carboransubstituenten CB11Cl11− an ein AuI‐Ion entsteht, zeigt die höchste je beschriebene Aktivität in der Hydroaminierung von Alkinen mit Aminen (siehe Schema). Die höchste Wechselzahl, die mit diesem Katalysator in der Hydroaminierung beobachtet wurden,...
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