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The reduction of (+)-camphorquinone by the plant pathogen Glomerella cingulata produced (+)-2-exo-3-exo-2,3-diol with high stereoselectivity, whereas (-)-camphorquinone yielded (+)-2-endo-3-exo-2,3-diol with high stereo- and enantioselectivity.
(+)- and (-)-Camphorquinones were readily reduced by various fungi. The reduction of (-)-camphorquinone by Aspergillus niger produced mainly (+)-2R-endo-hydroxyepicamphor with high stereoselectivity whereas reduction of (+)-camphorquinone by Glomerella cingulata and Mucor mucedo afforded (-)-3S-exo-hydroxycamphor with stereoselectivity.
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