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Porphyrin‐Based Metal–Organic Frameworks
A major challenge in studying Zr‐porphyrin‐based metal–organic frameworks (MOFs) is the poor reproducibility of reported syntheses. Article number 2210613 by Bettina V. Lotsch and co‐workers investigates the formation of Zr‐MOF particles step‐by‐step to understand and ultimately control the critical stages during nucleation and growth. Notably, water is essential...
Controlled synthesis of phase‐pure metal–organic frameworks (MOFs) is essential for their application in technological areas such as catalysis or gas sorption. Yet, knowledge of their phase formation and growth remain rather limited, particularly with respect to species such as water whose vital role in MOF synthesis is often neglected. As a consequence, synthetic protocols often lack reproducibility...
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