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The molecular architecture effect on active structure of miscellaneous polynorbornenes (Scheme 1) was investigated with pendant α,β-unsaturated amide or ester groups via ring-opening metathesis polymerization (ROMP). Remarkable differences in the reactivity and polymerization behavior of active norbornenes depend on various molecular architectures. Polynorbornenes derived from active norbornenes with...
Living ring-opening metathesis polymerization (ROMP) of a norbornene derivative containing carbazole group, 5-(N-carbazolyl methylene)-2-norbornene (CbzNB), was carried out to prepare pervaporation membranes for aqueous alcohol solution separation. The linear dependence of the number average molecular weight (Mn¯) on the [M]/[I] ratio ([M], monomer concentration; [I], initiator concentration) and...
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