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Surfaces composed of self-assembled monolayers (SAM) on gold were used to study the influence on the crystal growth of iron oxide-hydroxide [FeO(OH)]. The self-assembled monolayer formation on gold evaporated on microscope glass slides was carried out with α,ω mercaptoalkane acids. The in-situ growth of iron oxide-hydroxide crystals on the substrates was induced through the hydrolysis reaction of...
We have studied the templated crystallization of the three polymorphs of calcium carbonate on self-assembled monolayers of ω-substituted alkylthiols on gold surfaces. Our interest has been to model biomineralization processes by examining the effect of structured organic templates on heterogeneous nucleation at the inorganic-organic interphase. The crystallization of the three polymorphs was carried...
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