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Amphiphilic block copolymers composed of poly(ethylene glycol) (PEG) and poly(2-phenyl-2-oxazoline) (PPhOx) with different molecular weights and compositions are synthesized. Their molecular characteristics are determined by size exclusion chromatography (SEC), proton nuclear magnetic resonance (1H NMR), and Fourier transform infrared spectroscopy (FTIR). In aqueous solutions, the size of the formed...
We present the kinetics of temperature response of a PEO-b-PNIPAM-b-PAA triblock terpolymer and of its complexes with lysozyme in aqueous solution. It is found that during the coil-to-globule transition of PNIPAM new bonds within the polymer aggregates are created, making the transition of the aggregates partially irreversible. This effect is also found for the protein loaded PEO-b-PNIPAM-b-PAA aggregates...
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