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Packing Structures
The sandwich herringbone structure of pyrene is effectively “manipulated” by four‐fold methylthiolation by Kazuo Takimiya and co‐workers in article number 2102914 to realize a new‐type of a brickwork packing structure, which turns out to be an ideal channel material for single‐crystal organic‐field‐effect transistors, showing mobility higher than 30 cm2 V−1 s−1 and band‐like transport...
Control and prediction of crystal structures of molecular semiconductors are considered challenging, yet they are crucial for rational design of superior molecular semiconductors. It is here reported that through methylthiolation, one can rationally control the crystal structure of pyrene derivatives as molecular semiconductors; 1,6‐bis(methylthio)pyrene keeps a similar sandwich herringbone structure...
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