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Kinetic studies of vinyl acetate (VA) synthesis were carried out for Pd (1.0 wt%)/SiO 2 and Pd (1.0 wt%)–Au (0.5 wt%)/SiO 2 catalysts, with highly dispersed metal particles (Pd and Pd–Au) characterized by X-ray diffraction and transmission electron microscopy–energy dispersive spectroscopy (TEM-EDS). The kinetics of the related CO oxidation reaction were also explored. The kinetics...
Pd catalysts with varying particle size supported on a high-surface-area (600 m 2 /g) SiO 2 were prepared by wet impregnation. The kinetics of vinyl acetate (VA) synthesis at atmospheric pressure was investigated in a fix-bed microreactor. With transmission electron microscopy (TEM), the average diameter of the Pd particles was estimated to be 4.0±0.2 and 2.5±0.1 nm over the reduced...
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