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Ein naher Verwandter des Diazids: Azidoisocyanat, N3‐NCO, wurde durch den stufenweisen photoinduzierten Zerfall von Carbonyldiazid, CO(N3)2, gebildet und durch Matrix‐IR‐ und UV/Vis‐Spektroskopie sowie DFT‐Rechnungen charakterisiert (siehe Schema). Das Azidocarbonylnitren‐Intermediat N3C(O)N wurde ebenfalls charakterisiert.
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