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A novel interfacial compatibilization technique for incompatible polymer blends or composites is proposed, in which a transitioning layer was introduced between the matrix and the dispersed phase of the otherwise incompatible components. The transitioning phase should have good interactions with both the components, resulting in lower interfacial energy between the phases. Theoretically, it is hypothesized...
Novel organic–inorganic nanocomposites were prepared by in situ curing of poly(amic acid) macromolecules with POSS epoxide, octa(ethylcyclohexylepoxidedimethylsiloxy) silsesquioxane (OC). Solid-state 29 Si NMR data show that properties of the interphase can be varied systemically by adjusting the nano-tether structure of the POSS molecules. DMA studies conclude that the cross-linking densities...
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