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Decyl‐, dodecyl‐, and tetradecyltrimethylammonium cations were combined with the catalytic polyoxometalate [PW12O40]3− anion to give spherical and monodisperse nanoparticles that are able to stabilize emulsions in the presence of water and an aromatic solvent. This triphasic liquid/solid/liquid system, based on a catalytic surfactant, is particularly efficient as a reaction medium for epoxidation...
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