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The molecular structure of cis-sulfanuric fluoride was determined in the solid state by low temperature X-ray crystallography and in the gas-phase by electron diffraction. The results of both structure investigations are in close agreement. The six-membered sulfur-nitrogen ring is slightly puckered with NSNS dihedral angles of 34.5(10)° (crystal) and 24.5(48)° (gas) and S-N bond lengths of 1.553(3)...
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