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β-naphthalene sulfonyl fluoride, β-NaphSF, and β-naphthalene sulfonyl chloride, β-NaphSCl, were studied by gas-phase electron diffraction (GED) and quantum chemical calculations (B3LYP and MP2 in combination with cc-pVDZ, aug-cc-pVDZ and cc-pVTZ basis sets). For each compound the calculations predicted the existence of two conformers which are enantiomers. On the basis of the experimental data it...
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