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The engineering of robust protein/nanomaterial interfaces is critical in the development of bioelectrocatalytic systems. We have used computational protein design to identify two amino acid mutations in the small laccase protein (SLAC) from Streptomyces coelicolor to introduce new inter‐protein disulfide bonds. The new dimeric interface introduced by these disulfide bonds in combination with the...
Glucose oxidase catalyzes the formation of metallic gold particles in immediate proximity of the protein from gold (III) chloride in the absence of any other catalytic or reductive substrates. The protein‐mediated gold reduction reaction leads to size‐controllable gold particle formation and concomitant association of the enzyme in an electrically conductive metallic template. Such an enzyme immobilization...
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