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The short-range structures of fluorine–graphite intercalation compounds with stage-1 structures, C x F (x=2.47, 2.84, 3.61), were analyzed by means of neutron diffraction. It has been shown that the so-called “semi-ionic” C–F bond character in C x F is essentially covalent with the bond length of 0.140nm, and the original planar graphene sheets are buckled at the sp 3 -hybridized...
The short-range structures of the so-called graphite fluorides, poly(dicarbon monofluoride) ((C 2 F) n ) and poly(carbon monofluoride) ((CF) n ), have been discussed, based on the neutron diffraction data. The C–C and C–F bond lengths in these compounds are determined to be 0.157–0.158 and 0.136 nm, respectively, which slightly differ from those previously evaluated and coincide...
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