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Conformational properties and molecular structure of N-cyclohexylpiperidine (NCHP) were studied by quantum chemical calculations (DFT-B3LYP and MP2), gas-phase electron diffraction (GED–MS) and IR spectroscopy. NCHP may exist in at least eight conformeric forms that differ by their axial and/or equatorial positions and the relative orientation of the two rings. Two of these conformers were found to...
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