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The new ZIF named UZAR-S13 is formed by Zn2+ and 4(5)-(hydroxymethyl)imidazolate. UZAR-S13 has two distinct phases according to SEM and XRD: amorphous spheres and sheet crystals. UZAR-S13 and byproducts, with no N2 adsorption, rendered a notable CO2 uptake (up to 3.8mmolg−1 at 30bar and 0°C), approaching values of known ZIFs. The most promising materials were included as fillers in mixed matrix membranes...
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