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The effect of alkyl substituents at the C(5) position of isophthalic acid in the self-assembly of the title compounds is discussed with the aid of seven new crystal structures. The formation of channel-type (6 =< n < 12) and sheet-type (n >= 12) structures from 5-alkoxyisophthalic acids (CnISAs) in the crystal lattice is described. One of the reasons proposed for the formation of the cyclic...
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