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We prepared a two-station axis molecule possessing a 2-methylpyridinium moiety at an end, which regulates the direction of inclusion by α-cyclodextrin (α-CD). In the two-station axis molecule, the two decamethylene station moieties are linked through a pyridinium, over which α-CD can shuttle rather freely between the stations. We observed the formation of pseudo-rotaxane from the two-station axis...
Branched supramolecular polymers have been prepared from the mixture of 3-cinnamamide-α-CD (1) and 3-N α -cinnamamidehexancarbonyl-N ɛ -cinnamamide-lysinamide-α-CD (3) and from the mixture of 3-cinnamamidehexanamide-α-CD (2) and 3. Compounds 1 and 2 formed a linear supramolecular polymer, whereas compound 3 having two guest moieties formed a hyperbranched supramolecular polymer. Physical...
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