The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
Electrochemical reduction of 1-chloro-10-methyltribenzotriquinacene in benzonitrile, acetonitrile and N,N-dimethylformamide (DMF) is compared. A two-electron DISP1 mechanism was found in C 6 H 5 CN at glassy carbon and mercury electrodes with C–Cl bond cleavage as the rate determining step. In CH 3 CN and DMF the hydrogen atom abstraction from solvent molecules by a radical...
The electrochemical reduction of 1-chloro-, 1,4-dichloro- and 1,4,7-trichloro-10-methyl-tribenzotriquinacenes in ACN and DMF was found to occur by concerted electron transfer and bond breaking process, showing irreversible cyclic voltammetric peaks. However, the transition of the process to the stepwise mechanism upon increasing the driving force by raising the scan rate was established. Both CCl...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.