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Six cis-dioxomolybdenum(VI) complexes of simple monosaccharides (d-glucose, d-fructose, d-galactose, d-mannose, d-ribose and d-xylose) have been synthesized and characterized by a variety of analytical and spectral methods. Both the solution and solid-state studies have supported the presence of dimeric structures, formed through the cis-MoO 2 moieties and the bridging saccharide units. Solution...
Low molecular weight, water-soluble saccharide complexes of oxovanadium(IV) have been synthesized and characterized by analytical, spectroscopic and electrochemical techniques. All the complexes were found to be mononuclear, possessing the VO 2+ moiety. These are shown to be hydrolytically and oxidatively stable over a wide range of pH (1-12) and have been extensively characterized...
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