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Direct partial oxidation of CH 4 into synthesis gas has been studied by using an Rh|YSZ|Ag electrochemical reactor. Oxygen was pumped from the Ag cathode to the Rh anode through the YSZ to produce adsorbed oxygen species on the surface of the Rh anode. The adsorbed oxygen species can oxidize CH 4 to CO/H 2 directly, i.e. not via combustion of CH 4 to CO 2 and...
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