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A novel transformation of α-substituted benzylcyanides by hydroxylation of benzyl sites using cultured cells of cotton, Gossypium hirsutum, producing alkano- or benzophenones via presumably α-cyanohydrin is demonstrated. Also regioselective hydroxylation of 4S-(-)-perillyl alcohol and 3S-(-)-citronellol by cultured suspension cells of Catharanthus roseus is reported.
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