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The synthesis of four bifunctionalized orthogonally N-protected oligosaccharides derived from lactose and mannose, intended as cross-linking derivatives, is described. The aminosugar at the non-reducing end is derivatized with an N-Boc-protected glycine moiety, and further connected to either a mannose (1→6) disaccharide or (1→3) lactose units (one, two or three) resulting in tri-, penta-, or heptasaccharides...
Synthesis of three galactoglycerolipids (3-O-(β-d-galactopyranosyl)-1-O-hexadecyl-2-O-palmitoyl-sn-glycerol, 3-O-(α-d-galactopyranosyl-(1->4)-β-d-galactopyranosyl)-1-O-hexadecyl-2-O-p almitoyl-sn-glycerol, 3-O-(α-d-galactopyranosyl-(1->4)-β-d-galactopyranosyl)-1-O-hexadecyl-sn-gl ycerol), and the corresponding glycerolipid (1-O-hexadecyl-2-O-palmitoyl-sn-glycerol) is described. The first two...
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