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The hydrogenation of acrylamides using chiral Rh(I) complexes is an attractive method for the enantioselective synthesis of highly functionalized intermediates. It has been employed less frequently than the related Rh(I) catalyzed hydrogenation of enamides and the mechanism of the reaction is not well understood. The parent reaction of acrylamide with a simple Rh(I) bisphosphine complex was studied...
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