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Under the conditions of low-energy collision-induced dissociation (CID), the canonical glycylphosphoserinyltryptophan radical cation having its radical located on the side chain of the tryptophan residue ([GpSW]•+) fragments differently from its tautomer with the radical initially generated on the α-carbon atom of the glycine residue ([G•pSW]+). The dissociation of [G•pSW]+ is dominated by...
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