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The photoinduced reorientation behaviors of liquid crystalline (co)polymethacrylates (LCPs) comprised of N-benzylideneaniline (NBA) and 4-cyanobiphenyl or 4-methoxybiphenyl side groups are compared using linearly polarized (LP) 313 nm and LP 365 nm light. LCP films realize effective cooperative reorientation based on trans-cis-trans photoisomerization of the NBA moieties using LP 365 nm light and...
A new photo-cross-linkable liquid crystalline polymer (PLCP) comprised 4-methoxycinnamoyloxy groups connected with a bistolane side group was synthesized to investigate thermally enhanced photoinduced molecular reorientation of a thin film with linearly polarized (LP) 365nm light exposure. Due to the axis-selective photoreaction of the cinnamate groups followed by the thermally induced self-organization,...
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