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Divergent synthesis of fluorine‐containing scaffolds starting from a suite of raw materials is an intriguing topic. Herein, we report the solvent‐controlled rhodium‐catalyzed tunable arylation of 1‐bromo‐2,2‐difluoroethylene. The selection of the reaction solvents provides switchable defluorinated or debrominated arylation from readily available feedstock resources (both arylboronic acids/esters and...
Divergent synthesis of fluorine‐containing scaffolds starting from a suite of raw materials is an intriguing topic. Herein, we report the solvent‐controlled rhodium‐catalyzed tunable arylation of 1‐bromo‐2,2‐difluoroethylene. The selection of the reaction solvents provides switchable defluorinated or debrominated arylation from readily available feedstock resources (both arylboronic acids/esters and...
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