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Charcoal supported metal salt catalysts showed activities for the lignin gasification at 673 K, especially the catalysts without chloride anion showed the complete gasification. The order of activity for the gasification among the metal species was following: ruthenium > rhodium > platinum > palladium ~ nickel. X-ray absorption fine structure analysis revealed that small metal particles were...
High-temperature liquid water treatment of triol compounds [1,2,3-propanetriol (glycerol), 1,2,4-butanetriol (1,2,4-BTO), and 1,2,5-pentanetriol (1,2,5-PTO)] was carried out using a batch reactor. Intramolecular dehydration to hydroxyacetone from glycerol, 3-hydroxytetrahydrofuran from 1,2,4-BTO, and both tetrahydrofurfuryl alcohol and 3-hydroxytetrahydropyran from 1,2,5-PTO proceeded in water at...
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