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Three new ruthenium(II) complexes which contain two 1,10-phenanthroline units and a third bis-thioether chelate have been prepared and characterized. For two complexes, the X-ray structure shows a perfect fit between the two phen ligands and the bis-thioethers, with almost perfect C 2 symmetry for the Ru(phen) 2 unit and the S-containing ligand. This geometrical complementarity is...
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