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The orthopalladation of benzylamine (baH) by Pd(II) acetate in acetonitrile occurs in two time-resolved steps. A first faster step taking place at 25 o C results in the formation of the N-bound complex [Pd(OAc) 2 (baH) 2 ] and follows a second-order kinetics in the incoming amine according to the rate law k obs =k 1 [baH] 2 . The second order...
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