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Gold‐catalyzed cascade cyclization/1,2‐rearrangement of 1‐(2‐furanyl)phenyl propargyl alcohols has been developed, which provides a rapid and efficient access to multisubstituted 1‐naphthols bearing an enal or enone moiety with high stereoselectivity. The (Z)‐ or (E)‐stereochemistry can be easily controlled by choosing protected‐ or non‐protected substrates. The utility of the methodology has been...
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