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Die Mn+OH‐Einheit in einem Mangan(IV)‐Komplex hat ein stärkeres Elektronentransfervermögen als die Mn+O‐Einheit. Eine Mn+O‐Einheit kann ein Wasserstoffatom von einem Substrat abstrahieren und anschließend mit der OH‐Gruppe des gebildeten M(n−1)+OH an das nun radikalische Substrat binden. Setzt man dagegen ein Mn+OH‐Zentrum ein, so kann die reduzierte M(n−1)+OH2‐Gruppe dieses Zurückbinden nicht eingehen...
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