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At sixes and sevens: The reaction of corannulene with 35 equivalents of 1,4‐C4F8I2 is an efficient and a relatively selective process that yields two main products in which six H atoms are substituted with three C4F8 moieties that form six‐ and seven‐membered rings. Low‐temperature photoelectron spectroscopy showed the electron affinity of the major isomer (shown) exceeds that of C60 (2.74±0.02 and...
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