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Double take: β‐Borylallylsilanes have been synthesized by the regioselective silaboration of terminal alkynes followed by palladium‐catalyzed double‐bond migration of the resulting β‐borylalkenylsilanes (see scheme). The stereoselectivity of the double‐bond migration can be controlled by additives, thus leading to the stereocomplementary synthesis of (E)‐ and (Z)‐β‐borylallylsilanes.
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