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Berylliant! Interaction of a well‐defined adduct of MeBeH and an N‐heterocyclic carbene (NHC) with PhSiH3 results in complete rupture of the heterocycle, and activation of the NHC through effective BeH2 insertion into a CN bond of the heterocycle (see scheme; Ar=2,6‐diisopropylphenyl, IPr=1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene).
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