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The synthesis and crystal structures of three new metal organic frameworks of type [Zn(L-2H)]n (1), {[ZnLCl2](CH3CN)0.5(DMF)0.5(H2O)0.5}n (2) and {[CdL(DMF)(NO3)2]·DMF}n (3), all based on the dipyridyl-derivatised macrocycle, dipyridyldibenzotetraaza[14]annulene (L), are reported along with the X-ray structure of the protonated metal-free ligand as its perchlorate salt, [(HL)(ClO4)]n (4)....
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