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The effects of orientational selectivity on the 4-pulse electron electron double resonance (PELDOR) ESR spectra of coupled Cu(II)–Cu(II) spins are presented. The data were collected at four magnetic fields on a poly-proline peptide containing two Cu(II) centers. The Cu(II)–PELDOR spectra of this peptide do not change appreciably with magnetic field at X-band. The data were analyzed by adapting the...
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