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The cationic complex [(Et 2 N) 3 U][BPh 4 ] reacts with a mixture of terminal alkynes inducing the synthesis of the cross dimerization products. For equimolar amounts of aliphatic alkynes ( i PrC CH, t BuC CH) the head-to-tail geminal dimer of i PrC CH and the geminal cross dimer resulting from the insertion of i PrC CH into the U C CR...
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