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Keine Spur: Die Borylierung des Stickstoffatoms in Stickstoffheterocyclen oder Anilinen liefert eine spurlose dirigierende Gruppe für die anschließende katalytische C‐H‐Borylierung. Selektivitäten, für die früher Boc‐Schützung notwendig war, können erzielt werden; zudem kann die NBpin‐Schutzgruppe in situ aufgebaut und entfernt werden, und die erzielten Ausbeuten sind deutlich höher. Boc=tert‐Butoxycarbonyl,...
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