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Herein, we reported solid supramolecular bromonaphthylpyridinium polymers (P‐BrNp), which exhibit tunable phosphorescence emission in the amorphous state enabled by sulfobutylether‐β‐cyclodextrin (SBE‐β‐CD) and diarylethene derivatives. The monomer BrNp gave single fluorescence emission at 490 nm, while an apparent room‐temperature phosphorescence (RTP) at 550 nm emerged for P‐BrNp copolymers with...
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