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The mechanism of electron transfer of several diquaternary salts of 4,4 -bipyridine and 2,2 -bipyridine with the FAD which is the prosthetic group of the protein ferredoxin-NADP + reductase from the cianobacterium Anabaena PCC 7119 was studied. Two different reactions involving the same compounds were studied: (i) the reduction of NADP + by the enzyme using reduced viologens; (ii)...
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